全文获取类型
收费全文 | 5551篇 |
免费 | 57篇 |
国内免费 | 120篇 |
专业分类
系统科学 | 57篇 |
丛书文集 | 111篇 |
教育与普及 | 104篇 |
理论与方法论 | 8篇 |
现状及发展 | 1981篇 |
研究方法 | 218篇 |
综合类 | 3236篇 |
自然研究 | 13篇 |
出版年
2021年 | 48篇 |
2014年 | 49篇 |
2013年 | 54篇 |
2012年 | 95篇 |
2011年 | 140篇 |
2010年 | 85篇 |
2009年 | 143篇 |
2008年 | 155篇 |
2007年 | 199篇 |
2006年 | 115篇 |
2005年 | 162篇 |
2004年 | 161篇 |
2003年 | 117篇 |
2002年 | 121篇 |
2001年 | 252篇 |
2000年 | 222篇 |
1999年 | 231篇 |
1998年 | 85篇 |
1997年 | 86篇 |
1996年 | 66篇 |
1995年 | 74篇 |
1994年 | 48篇 |
1992年 | 129篇 |
1991年 | 124篇 |
1990年 | 115篇 |
1989年 | 86篇 |
1988年 | 93篇 |
1987年 | 88篇 |
1986年 | 61篇 |
1985年 | 99篇 |
1984年 | 81篇 |
1983年 | 62篇 |
1982年 | 65篇 |
1981年 | 59篇 |
1980年 | 75篇 |
1979年 | 146篇 |
1978年 | 134篇 |
1977年 | 107篇 |
1976年 | 79篇 |
1975年 | 73篇 |
1974年 | 98篇 |
1973年 | 103篇 |
1972年 | 89篇 |
1971年 | 111篇 |
1970年 | 100篇 |
1969年 | 96篇 |
1968年 | 95篇 |
1967年 | 87篇 |
1966年 | 86篇 |
1965年 | 58篇 |
排序方式: 共有5728条查询结果,搜索用时 18 毫秒
51.
The relaxation of the highly vibrationally excited CO (v = 1–8) by CO2 is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture
of CHBr3 with O2 generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The
vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution
of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO2 molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (1014 cm3 · molecule−1 · s−1), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO2. For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u3 mode of CO2 For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u1 mode of CO2. 相似文献
52.
The vibrational energy transfer from highly vibrationally excited CO to H2O molecules is studied by time-resolved Fourier transform infrared emission spectroscopy (TR FTIR). Following the 193 nm laser
photolysis of CHBr3 and O2 the secondary reactions generate CO(v). The infrared emission of CO(v → v−1) is detected by TR FTIR. The excitation of H2O molecules is not observed. By the method of the spectral simulation and the differential technique, 8 rate constants for
CO(v)/H2O system are obtained: (1.7 ±0.1), (3.4 ±0.2), (6.2 ±0.4), (8.0 ±1.0), (9.0 ±2.0), (12 ±3), (16 ±4) and (18 ±7) (1013cm3 · molecule-1· s-1). At least two reasons lead to the efficient energy transfer. One is the contributions of the rotational energy to the vibational
energy defect and the other is the result of the complex collision. With the SSH andab initio calculations, the quenching mechanism of CO(v) by H2O is suggested. 相似文献
53.
Lili Tian Jiyang Wang Jingqian Wei Henfu Pan Qingcai Guan Xiaobo Hu Yaogang Liu C. Q. Wang Y. T. Chow 《科学通报(英文版)》1998,43(23):1973-1973
The optical properties of Nd x Gd 1-x Al\-3(BO\-3)\-4 (NGAB) crystal are reported. The refractive index of it were mesured by V_prism method. The absorption spectra and the flourescence specra of NGAB were also obtained. The optical parameters of NGAB were calculated following J_O theory, the three optical parameters are Ω 2 =1 805×10 -20 , Ω 4=1 85×10 -20 , Ω 6=3 793×10 -20 (RMS=1 4×10 -7 ) and β c( 4F 3/2 → 4I 11/2 ) is about 0 53. 相似文献
55.
利用真实砂岩微观孔隙模型研究粘性不稳定指进 总被引:8,自引:0,他引:8
朱玉双 《西北大学学报(自然科学版)》1998,28(2):166-168
利用真实砂岩微观孔隙模型进行了不同油水粘度比下的油水两相驱替试验,研究了粘性不稳定指进;提出了控制注入水粘性指进的注入速度及油水粘度比的要求,对指导油田生产有一定的意义。 相似文献
56.
57.
Summary 7 monoterpenes, -pinene, -pinene, myrcene, p-cymene, limonene, neral and geranial, were identified together with n-undecane in the scent scales ofP. melete, and also, together with considerable amounts of linalool, in the scent scales ofP. napi. Content ratio of neral to geranial inP. melete ranged from 0.77 to 1.04, and that inP. napi from 1.84 to 2.43. The present chemotaxonomic approach shows the 2 species ofPieris to be distinct.The authors thank Dr T. Yushima (National Institute of Agricultural Science, Japan) for supplying the references 3 and 4. 相似文献
58.
At ambient temperatures (Ta) of both 8 and 22 degrees C, intraventricular administration of TRH (10-80 microgram) produced a dose-dependent hypothermia in rats. The hypothermia was due to both decreased metabolic heat production and cutaneous vasodilatation. In contrast, at 30 degrees C Ta, TRH increased metabolic heat production (due to behavioral excitation) and led to hyperthermia. 相似文献
59.
Summary The C-terminal amino acid sequences of human and of porcine antithrombin III have been determined as Gly-Arg-Val-Ala-Asn-Pro-Cys-Val-Lys and Gly-Arg-Val-Ala-Asn-Pro-Cys, respectively. These sequences are highly homologous with the C-terminal sequence of human -1-proteinase inhibitor. 相似文献
60.
Summary 2-Halogeno-ethanols change the active site structure of -chymotrypsin more rapidly and effectively than ethanol, 1-propanol and urea, probably before producing an extensive conformation change. 相似文献